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By
Steven Luff, published in Health Supplement Retailer magazine
August 1999.
There
are two types of decaffeination processes used in tea. One
is accomplished using ethyl acetate, an organic [chemical]
solvent, and the other is with carbon dioxide. With ethyl
acetate, the tea is moistened and the solvent is passed through
the leaves. As it passes through, the ethyl acetate takes
the caffeine with it. Ultimately, the tea is heated to remove
[most] of the remaining chemical residues and then is dried.
In carbon dioxide decaffeination, moistened tea leaves are
put under heat and pressure and treated with carbon dioxide
gas. The carbon dioxide mixes with the caffeine, and when
it is released to the atomsphere, it takes the caffeine with
it.
Both
of these options are successful in removing caffeine from
tea leaves, but only the carbon dioxide process preserves
the majority of the medicinal integrity. EGCG, along with
other medicinally significant flavonoids found in tea, is
water soluble. Therefore, any decaffeination process involving
water will remove these components at the same time it removes
the caffeine. Ethyl acetate does this when it bonds with the
caffeine. Carbon dioxide, however, does not interfere with
the flavonoids.

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